2.将聚乙烯醇胶水投入不锈钢反应釜(也可用搪瓷反应釜,只是搪瓷釜的传热效果不及不锈钢反应釜),再加入乳化剂OP-10,开动搅拌机,使之混合均匀。
3.将聚醋酸乙烯酯单体总量的15%(即6.9)与过硫酸钾配方量的40%(即0.036)加入不锈钢反应釜中,继续搅拌,并开始升温。当温度升到60-65℃停止加热。其中要注意,引发剂过硫酸钾应先用纯水兑成8%~10%的水溶液,分多次加完。
4.在引发剂的作用下,虽停止加热,但温度自行升高,当温度在65℃以上时,反应釜的回流装置开始出现回流。当温度升到80℃以上时回流逐渐减弱。此时从反应釜的滴加斗中,进行聚醋酸乙烯酯单体的滴加,滴加速度应控制在每小时滴加总量的10%左右(即4.6左右)。在反应过程中,要密切注意反应温度,在反应釜夹套中加入冷却水来控制反应温度,不高于80℃。
5.在加醋酸乙烯酯单体的同时,也加入引发剂,每小时加入量为配方量的4.5%左右。
6.醋酸乙烯酯和引发剂都应控制在8h左右加完。由于引发剂的作用,反应较强烈,单体加完后,反应温度会自行上升,当上升至93℃左右时,保温30min。聚合反应基本完成。
7.打开冷却水,使不锈钢反应釜内温度降低,降到50℃以下时,加入碳酸氢钠水溶液(应预先溶化10%浓度)和邻苯二甲酸二丁酯,pH值调到6~7为止。
8.不锈钢反应釜的搅拌机始终不能停,当冷却至室温时,得白乳胶成品,停止搅拌,放料、包装。
9.当白乳胶成品的黏度过大、耐水性差时,可适当减少配方中聚乙烯醇的用量。
10.若白乳胶乳液稳定性差,可适当减少配方中一些引发剂的用量,太少时会不引发,造成单体难聚合。
11.邻苯二甲酸二丁酯用量不可过多,不要超过单体的10%,否则白乳胶成品的胶粘性下降,且增加了成本。它主要 作用是增加乳液的韧性和降低乳液的成膜温度。
12.如果白乳胶成品的泡沫较多,可加入适量消泡剂。
13.引发剂过硫酸钾的用量和添加时间应注意掌握,当开始出现回流时,若回流量大,表明引发剂没起到作用,单体过多,应停止加单体,可酌情增加一些引发剂,当回流正常时再加单体。
14.用上述白乳胶配方及制作方法生产的白乳胶为白色均匀的乳状液体,固体含量50%左右,pH值约为5。
另外,此白乳胶成品还可添加801胶水、锐钛型钛白粉生产改性白乳胶。
The following has evaluated to null or missing:
==> langConfig [in template "public_include/wap/module/version_1/language.html" at line 49, column 14]
----
Tip: If the failing expression is known to be legally refer to something that's sometimes null or missing, either specify a default value like myOptionalVar!myDefault, or use <#if myOptionalVar??>when-present<#else>when-missing</#if>. (These only cover the last step of the expression; to cover the whole expression, use parenthesis: (myOptionalVar.foo)!myDefault, (myOptionalVar.foo)??
----
----
FTL stack trace ("~" means nesting-related):
- Failed at: #if langConfig.status?string = "false" [in template "public_include/wap/module/version_1/language.html" at line 49, column 9]
- Reached through: #include "/public_include/wap/module/... [in template "tpl/2018/03/17/2613443926933696//wap/com_5.html" at line 5, column 1]
- Reached through: #include "com_5.html" [in template "tpl/2018/03/17/2613443926933696//wap/displaynews.html" at line 69, column 6]
----
Java stack trace (for programmers):
----
freemarker.core.InvalidReferenceException: [... Exception message was already printed; see it above ...]
at freemarker.core.InvalidReferenceException.getInstance(InvalidReferenceException.java:134)
at freemarker.core.UnexpectedTypeException.newDesciptionBuilder(UnexpectedTypeException.java:80)
at freemarker.core.UnexpectedTypeException.<init>(UnexpectedTypeException.java:43)
at freemarker.core.NonHashException.<init>(NonHashException.java:49)
at freemarker.core.Dot._eval(Dot.java:48)
at freemarker.core.Expression.eval(Expression.java:81)
at freemarker.core.BuiltInsForMultipleTypes$stringBI._eval(BuiltInsForMultipleTypes.java:692)
at freemarker.core.Expression.eval(Expression.java:81)
at freemarker.core.EvalUtil.compare(EvalUtil.java:111)
at freemarker.core.ComparisonExpression.evalToBoolean(ComparisonExpression.java:62)
at freemarker.core.ConditionalBlock.accept(ConditionalBlock.java:48)
at freemarker.core.Environment.visit(Environment.java:327)
at freemarker.core.Environment.visit(Environment.java:333)
at freemarker.core.Environment.include(Environment.java:2509)
at freemarker.core.Include.accept(Include.java:171)
at freemarker.core.Environment.visit(Environment.java:327)
at freemarker.core.Environment.visit(Environment.java:333)
at freemarker.core.Environment.include(Environment.java:2509)
at freemarker.core.Include.accept(Include.java:171)
at freemarker.core.Environment.visit(Environment.java:327)
at freemarker.core.Environment.visit(Environment.java:333)
at freemarker.core.Environment.process(Environment.java:306)
at freemarker.ext.servlet.FreemarkerServlet.processEnvironment(FreemarkerServlet.java:946)
at freemarker.ext.servlet.FreemarkerServlet.process(FreemarkerServlet.java:910)
at freemarker.ext.servlet.FreemarkerServlet.doGet(FreemarkerServlet.java:769)
at javax.servlet.http.HttpServlet.service(HttpServlet.java:622)
at javax.servlet.http.HttpServlet.service(HttpServlet.java:729)
at org.apache.catalina.core.ApplicationFilterChain.internalDoFilter(ApplicationFilterChain.java:292)
at org.apache.catalina.core.ApplicationFilterChain.doFilter(ApplicationFilterChain.java:207)
at org.apache.tomcat.websocket.server.WsFilter.doFilter(WsFilter.java:52)
at org.apache.catalina.core.ApplicationFilterChain.internalDoFilter(ApplicationFilterChain.java:240)
at org.apache.catalina.core.ApplicationFilterChain.doFilter(ApplicationFilterChain.java:207)
at com.kenfor.iyong.web.util.filter.NotAllowedToTunFilesFilter.doFilter(NotAllowedToTunFilesFilter.java:154)
at org.apache.catalina.core.ApplicationFilterChain.internalDoFilter(ApplicationFilterChain.java:240)
at org.apache.catalina.core.ApplicationFilterChain.doFilter(ApplicationFilterChain.java:207)
at com.kenfor.iyong.web.util.filter.InvalidXSSFilter.doFilter(InvalidXSSFilter.java:40)
at org.apache.catalina.core.ApplicationFilterChain.internalDoFilter(ApplicationFilterChain.java:240)
at org.apache.catalina.core.ApplicationFilterChain.doFilter(ApplicationFilterChain.java:207)
at org.springframework.web.filter.CharacterEncodingFilter.doFilterInternal(CharacterEncodingFilter.java:121)
at org.springframework.web.filter.OncePerRequestFilter.doFilter(OncePerRequestFilter.java:107)
at org.apache.catalina.core.ApplicationFilterChain.internalDoFilter(ApplicationFilterChain.java:240)
at org.apache.catalina.core.ApplicationFilterChain.doFilter(ApplicationFilterChain.java:207)
at org.apache.catalina.core.StandardWrapperValve.invoke(StandardWrapperValve.java:212)
at org.apache.catalina.core.StandardContextValve.invoke(StandardContextValve.java:106)
at org.apache.catalina.authenticator.AuthenticatorBase.invoke(AuthenticatorBase.java:502)
at com.orangefunction.tomcat.redissessions.RedisSessionHandlerValve.invoke(RedisSessionHandlerValve.java:26)
at org.apache.catalina.core.StandardHostValve.invoke(StandardHostValve.java:141)
at org.apache.catalina.valves.ErrorReportValve.invoke(ErrorReportValve.java:79)
at org.apache.catalina.valves.AbstractAccessLogValve.invoke(AbstractAccessLogValve.java:616)
at org.apache.catalina.core.StandardEngineValve.invoke(StandardEngineValve.java:88)
at org.apache.catalina.connector.CoyoteAdapter.service(CoyoteAdapter.java:528)
at org.apache.coyote.ajp.AbstractAjpProcessor.process(AbstractAjpProcessor.java:873)
at org.apache.coyote.AbstractProtocol$AbstractConnectionHandler.process(AbstractProtocol.java:687)
at org.apache.tomcat.util.net.NioEndpoint$SocketProcessor.doRun(NioEndpoint.java:1520)
at org.apache.tomcat.util.net.NioEndpoint$SocketProcessor.run(NioEndpoint.java:1476)
at java.util.concurrent.ThreadPoolExecutor.runWorker(ThreadPoolExecutor.java:1142)
at java.util.concurrent.ThreadPoolExecutor$Worker.run(ThreadPoolExecutor.java:617)
at org.apache.tomcat.util.threads.TaskThread$WrappingRunnable.run(TaskThread.java:61)
at java.lang.Thread.run(Thread.java:745)